Listed on the NSW State Heritage Register and with the Inner West Council as an item of High Local Significance, the building originally housed 10 Sisters of the Good Samaritan and 30 boarders, with an additional study hall able to seat 300.
At one time, a renovation divided the original convent into three residences, with the South Wing further split into three apartments. In a nod to preservation, a 2011 renovation gutted the apartments and reunited the space to its former/current form.